Watkins Factor: developing

Time of first appearance as estimator of developing time for that emulsion in that developer.

In re-working information about Deep/Thick vs Thin emulsions… da-net posers made me do it.

Deeper dive into Time-Temperature of photography.

  • Watkins
  • Sheppard and Meyer
  • Clerc, section 400, the influence of temperature
  • Clerc, section 380 & 381, watkins factors, & combined factors

How Does It Work?

Developing is a process of saturating the emulsion; surrounding the exposed material with fresh developer, then moving exhausted developer. This main process is agitation. The key part of the emulsion is the gelatin. Think of the emulsion as having depth, as well as surface. This emulsion, whether film or paper, has to absorb the fresh developer– this takes time. An induction time. How fast the exposed silver begins developing depends upon the strength (developing power) of the developer. It is affected by temperature, emulsion, etc, but the main factor was the developing agent(s) used.

The watkins method is mainly of use with emulsions suited to development by inspection. It is of great use in making lith negatives, or, somewhat, in making lith-prints. Sadly, in a developer containing two developing agents, the temperature coefficient loses significance when temperature varies much from 20 C.

Developing AgentC
Metol1.25
Paraminophenol1.5
Ferrous oxalate1.7
Pyrogallol1.9
Metol-hydorquinone1.9
Hydroquinone2.2 to 2.8
Catechol2.8

Some developing agents change activity with temperature — hydroquinone loses activity at low temperature. (Jacobsen, p.67)

Temperature coefficients vary slightly with emulsions. Concentration of developer has little effect.

The temperature coefficient of a developer is the increase in speed of development for a 10F increase. A TC of 2 means that a developer works twice as quickly at 75F as it does at 65F — typical Coefficients from the mid-century were: 1.8 for MQ developer(D76), for fine-grain developers (D23), and 2.3 for super-fine grain developer.

Note: pyro and amidol do vary by amount of grains per ounce. Bromide alters the pyro factor.

Compensating Timers

Temperature control is better than a compensating timer. Keeping agitation in line, changes of developer is more important to critical processing than is time-temperature duration. Build tray rockers, insulated, water-jacket trays with lids instead.

But, if you are interested search: Tundra. DLG. ProcessMaster.

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nutshell: Masking

an overview of masks: what they are; what they do. Masking is selective dodging.. consider it a precise, custom, graduated neutral density filter. Masks are most often used this century to alter contrast of B&W film. They also increase local contrasts, thereby altering edge effects making a print appear sharper with more gradations. These are the “unsharp masks (USM)”

In last century, during the growth stage of masking, they were used in color processes to alter, and correct contrast and color. Masking increased the contrast of the magenta and yellow, overcoming deficiencies, impurities of colorants.

If the original transparency isn’t underexposed, and the contrast of the scene is low, no masking is required.

Films I have today for masking: Ilford PanF (120). Ilford Delta 100 (4×5 & 8×10). Ilford Ortho+ (4×5, 8×10, special roll). Note the Ilford weight. I do, and it makes me nervous, since Ilford hangs on the interest of real estate ventures in a country of short term values.

From the past; more for the Rosetta stone. Translating data sheets. Why that film/developer was made.

From the past, The mask film used was Tri-X Plate. Masks were made using film available. No special film.

The layout, exposure configuration was typical Kodak method used and taught for over 40 years.

Pan Masking film in Versamat — was the standard method at the end of the Kodak Dye Transfer era.

Masks should never be greater than 40%. Coated (APO) lenses require higher percent masks.

The appearance of color swatches in separation negatives is best indicator of correct mask exposure.

Most of the original guidance assumed the use of the Standard Light.


Developer for masks, like those for seps should be non-staining and not “fine-grain” solvent type. It is easy to recommend DK-50, DK-60a as best options, even this decade. For ready mix, try HC-110 one-shot. All masks and seps should be processed following a one-shot protocol. Use the mixture one time and discard. I use fresh developer for each sheet of film.

FilterUse
F- 29 RedRequired
N- 61 GreenRequired
#96 Neutral density: 0.10 / 0.30 / 1.0Strongly recommended. Equalize exposures. Reduce reciprocity differences.
#33 Magentaoptional
#15 Yellowoptional
Filters for (color) masking

Be assured that masking cannot make a color that the dyes, if mixed outside the system, cannot produce. This is why we always tried for better and better dyes (colorants). To correct all the cross-talk of dyes, six masks are needed. Contrast of masks is proportional to errors of colorants being modified.

compensate blue and green in CYAN2 masks
compensate for MAGENTA2 masks
compensate for YELLOW2 masks
the gammas must be corrected for each change in original color (transparency). If the chrome’s emulsion or processing change, a new configuration of correction masks would be calculated. [see Friedman for method ]

Not a realistic effort. Particularly since most images/ viewer sets can’t discern the improvement in real world conditions.


MASKING COLOR NEGATIVES

footnote for ongoing readers: notation on confused Large format masking board:

board note: CN[C41] film is designed for printing using a ‘hot’ light onto a color print [RA4]. BW films are more sensitive than the intended color paper. Recent discussion has much alteration discussion. What they are achieving is on this blackboard exercise.

Removing the “Orange” mask: If you want this brightest color to have a neutral hue, you need to expose, such that Dred = Dgreen = Dblue = 0.9, i.e. a uniform gray strip with D = 0.9 will be the brightest neutral color you can create. With extra exposure you can then reach all colors in the range (Dred = 0.9, Dgreen = 0.9, Dblue = 0.9) + (ΔDred, ΔDgreen, ΔDblue) with ΔDred ≥ 0, ΔDgreen ≥ 0, ΔDblue ≥ 0.

1950.. D-76 the standard developer for separation negatives. Its alternates were the DKs. See the footnote above for target gammas.

There was no magic in separation negatives. It has always been a balance between exposure types, filters, film + developer + agitation method.

I rarely used Super-XX as a sep film; only when clients required it. And on a small year, I made around 200 first prints – this, during my first 5 years working.